RT Journal Article
T1 Mechanistic and Computational Studies of the Atom Transfer Radical Addition of CCl4 to Styrene Catalyzed by Copper Homoscorpionate Complexes
A1 Muñoz Molina, José María
A1 Saamera, W. M. C.
A1 Maseras, Feliu
A1 Rodríguez Belderraín, Tomás
A1 Pérez Romero, Pedro José
AB Experimental as well as theoretical studies have been carried out with the aim of elucidating the mechanism of the Atom Transfer Radical Addition (ATRA) of styrene and carbon tetrachloride with a TpxCu(NCMe) complex as the catalyst precursor (Tpx = hydrotrispyrazolyl-borate ligand). The studies shown herein demonstrate the effect of different variables in the kinetic behavior. A mechanistic proposal consistent with theoretical and experimental data is presented
SN 0020-1669
SN 1520-510X (electrónico)
YR 2011
FD 2011-02
LK http://hdl.handle.net/10272/11554
UL http://hdl.handle.net/10272/11554
LA eng
NO Muñoz Molina,J.M., Saamera, W.M.C., Maseras, F., Belderrain, T.R., Pérez Romero, P.J.: "Mechanistic and Computational Studies of the Atom Transfer Radical Addition of CCl4 to Styrene Catalyzed by Copper Homoscorpionate Complexes".  	Inorganic Chemistry. Vol. 50 (6), págs. 2458–2467, (2011). DOI: 10.1021/ic102279w
NO We thank the MICINN (Grants CTQ2008-00042BQU, CTQ2008-06866-CO2-02/BQU, and Consolider Ingenio 2010 CSD2006-0003) and the Junta de Andalucia (Proyecto P07-FQM-02794) for financial support.MICINN (Grants CTQ2008–00042BQU, CTQ2008-06866-CO2-02/BQU and Consolider Ingenio 2010 CSD2006-0003) and the Junta de Andalucía (Proyecto P07-FQM-02794)
DS Repositorio Institucional de la Universidad de Huelva
RD 31 may 2026