RT Journal Article
T1 Nitrene transfer reactions catalysed by copper(I) complexes in ionic liquid using chloramine-T
A1 Cano Rico, Israel
A1 Nicasio Jaramillo, María Carmen
A1 Pérez Romero, Pedro José
AB The complex [Tpm*,BrCu(NCMe)]BF4 (Tpm*,Br = HC(3,5-Me2-4-Br-pyrazolyl)3) catalyses the aziridination of alkenes and the amidation of cyclic ethers with chloramine-T as the nitrene source and the ionic liquid [bmim]PF6 as the reaction medium (bmim = 1-n-butyl-3-methylimidazolium). High conversions have been obtained over several cycles of catalyst recovery and reuse.
PB Royal Society of Chemistry
SN 1477-9226
SN 1477-9234 (electrónico)
YR 2008
FD 2008
LK https://hdl.handle.net/10272/22780
UL https://hdl.handle.net/10272/22780
LA eng
NO Cano, I., Nicasio, M. C., & Pérez, P. J. (2009). Nitrene transfer reactions catalysed by copper(I) complexes in ionic liquid using chloramine-T. In Dalton Trans. (Issue 4, pp. 730–734). Royal Society of Chemistry (RSC). https://doi.org/10.1039/b813469c
NO We thank the MEC (Proyecto CTQ2005-00324/BQU) and the Junta de Andalucía (Proyecto P07-FQM-02745) for financialsupport. IC thanks MEC for a research fellowship.
DS Repositorio Institucional de la Universidad de Huelva
RD 30 may 2026