@article{10272/17578,
year = {2002},
url = {http://hdl.handle.net/10272/17578},
abstract = {The statistical associating fluid theory for potentials of variable range (SAFT-VR) is used to examine the phase behaviour in the CO2 + n-alkane homologous series. A unique set of transferable parameters for the unlike inter- actions are used which allow the prediction of the phase behaviour of different members of the series with little experimental data. A change in phase behaviour from type II in the van Konynenburg scheme (continuous gas–liquid critical line and liquid–liquid immiscibility at low temperatures) for CO2 + n-dodecane, to type IV (discontinuous gas–liquid critical line and liquid–liquid immiscibility) for CO2 + n-tridecane, and to type III (continuous transi- tion from gas–liquid to liquid–liquid critical behaviour) for CO2 + n-tetradecane is observed in agreement with experimental data.},
organization = {F.J.B. would like to thank the Oil Extraction Program of the Engineering and Physical Sciences Research Council (EPSRC) for a research fellowship (GR/N20317), and A.G. would like to thank the EPSRC for the award of an Advanced Research Fellowship. This work has also been sponsored by a research project for the VII Plan Propio de Investigación of the University of Huelva (Spain). This financial support is gratefully acknowledged.},
publisher = {Elsevier},
title = {Study of the high pressure phase behaviour of CO2+n-alkane mixtures using the SAFT-VR approach with transferable parameters},
doi = {10.1016/S0378-3812(01)00651-3},
author = {Jiménez Blas, Felipe and Galindo, Amparo},
}