RT Journal Article
T1 Dimensioning the term carbenoid
A1 Caballero Bevia, Ana
A1 Pérez Romero, Pedro José
AB The current use of the term carbenoid isdiscussed, particularly in the context of carbene transferreactions from diazo compounds, where intermediates oftype LnM=CR1R2, or one of its resonance forms, are taggedwhich such name. We herein discuss this issue, on thebasis of the data evidencing the metal-carbene nature ofthose intermediates, as well as the existence of carbenoidsof type (N2)(M)C R1R2 en route to the formation to LnM=CR1R2’ from diazo reagents. We propose the exclusive use ofthe carbenoid term to species of type (X)(M)C R1R2 with atetrasubstituted carbon center that upon loss of X afford aneffective carbene transfer process.
PB Wiley
SN 0947-6539
SN 1521-3765 (electrónico)
YR 2017
FD 2017
LK http://hdl.handle.net/10272/16195
UL http://hdl.handle.net/10272/16195
LA eng
NO Caballero, A., & Pérez, P. J. (2017). Dimensioning the Term Carbenoid. Chemistry - A European Journal, 23(58), 14389–14393. https://doi.org/10.1002/chem.201702392
NO The authors wish to thank MINECO for financial support (CTQ2014-52769-C03-01) and Junta de Andalucia (P12-FQM-1765).
DS Repositorio Institucional de la Universidad de Huelva
RD 15 jun 2026