@article{10272/15974,
year = {2018},
url = {http://hdl.handle.net/10272/15974},
abstract = {We report quantitative measurements of the relative reactivities of a series of C-H bonds of gaseous or liquid CnH2n+2 alkanes (n = 1-8, 29 different C-H bonds) towards insitu generated electrophiles (copper, silver, and rhodium carbenes), with methane as the reference. This strategy surpasses the drawback of previous model reactions of alkanes with strong electrophiles suffering from C-C cleavage processes, which precluded direct comparison of the relative reactivities of alkane C-H bonds.},
organization = {We thank MINECO for support with Grants CTQ2014-52769-C03-01, CTQ2014-52769-C03-02, CTQ2017-82893-C2-1-R, CTQ2014-62234-EXP, CTQ2015-73693-JIN, CTQ2017-87792-R, Severo Ochoa Excellence Accreditation 2014-2018 (SEV-2013-0319), and Red Intecat (CTQ2016-81923-REDC). Junta de Andalucia is also acknowledged for Grant P12-FQM-1765. R.G. and A.O. thank MINECO for FPI and Juan delaCierva fellowships, respectively. B.N. thanks MEC for a FPU fellowship. The CNRS is thanked for support.},
publisher = {Wiley},
title = {Measuring the Relative Reactivity of the Carbon-Hydrogen Bonds of Alkanes as Nucleophiles},
doi = {10.1002/anie.201807448},
author = {Olmos Verge, Andrea and Gava, Riccardo and Caballero Bevia, Ana and Pérez Romero, Pedro José},
}