RT Journal Article
T1 Catalytic Functionalization of C-H Bonds of Azulene by Carbene/Nitrene Incorporation
A1 Carreras, Javier
A1 Popowski, Yanay
A1 Caballero Bevia, Ana
A1 Amir, Elizabeth
A1 Pérez Romero, Pedro José
AB The selective catalytic functionalization of the C-H bond of azulene upon incorporation of carbene or nitrene units with metal-based catalysts is described. Ethyl diazoacetate or ArI=NTs are employed as carbene or nitrene precursors, respectively. The azulene derivatives are subsequently employed as building blocks toward more complex structures with potential use as biodegradable materials.
PB American Chemical Society
SN 0022-3263
SN 1520-6904 electrónico
YR 2018
FD 2018
LK http://hdl.handle.net/10272/15973
UL http://hdl.handle.net/10272/15973
LA eng
NO Carreras, J., Popowski, Y., Caballero, A., Amir, E., & Pérez, P. J. (2018). Catalytic Functionalization of C–H Bonds of Azulene by Carbene/Nitrene Incorporation. The Journal of Organic Chemistry, 83(18), 11125-11132. https://doi.org/10.1021/acs.joc.8b01731
NO We thank MINECO (CTQ2017-82893-C2-1-R and Juan de la Cierva fellowship for J.C.), Junta de Andalucia for Grant P12-FQM-1765, and CHAOS COST ACTION CA-15106. We also thank Manuel A. Pulido for preliminary experiments and Francisco Molina for X-ray structure determination.
DS Repositorio Institucional de la Universidad de Huelva
RD 14 jul 2026