RT Journal Article
T1 An algebraic approach applied to the determination of the polarizability in CO2
A1 Lemus, R.
A1 Sánchez Castellanos, M.
A1 Carvajal Zaera, Miguel
AB A local algebraic approach to describe vibrational excitations of moleculespresenting both local and normal mode behaviors is presented. This approach allows theconnection with configuration space to be established. The model consists in expandingthe kinetic energy as well as the potential in terms of coordinates and momenta. Analgebraic representation is obtained by introducing creation and destruction bosonic operatorsassociated with the harmonic oscillators. From the resulting Hamiltonian a local algebraicrepresentation is obtained through a canonical transformation to local bosonic operators. Finallyan anharmonization is carried out by changing the local bosonic operators to ladder operatorsassociated with the Morse or P¨oschl-Teller functions. Since the model is connected withconfiguration space, non linear curvilinear coordinates are contemplated. Our model is appliedto the vibrational spectroscopic description of the 12C16O2 molecule. The eigenstates are testedby calculating the derivatives for the polarizability for this molecule.
PB IOP Publishing
SN 1742-6588
SN 1742-6596
YR 2014
FD 2014
LK http://hdl.handle.net/10272/8263
UL http://hdl.handle.net/10272/8263
LA eng
DS Repositorio Institucional de la Universidad de Huelva
RD 30 may 2026