RT Journal Article T1 Combining vegetable oils and bioactive compounds via inverse vulcanization for antioxidant and antimicrobial materials A1 Cubero Cardoso, Juan A1 Gómez-Villegas, Patricia A1 Santos Martín, María A1 Sayago Gómez, Ana A1 Fernández Recamales, María Ángeles A1 Fernández de Villarán San Juan, Rubén A1 Cuadri Vega, Antonio Abad A1 Martín Alfonso, José Enrique A1 Borja Padilla, Rafael A1 González Fermoso, Fernando A1 León Bañares, Rosa María A1 Urbano Baena, Juan AB The current great concern about plastic pollution opens up opportunities for the production of more sustainable polymers. Inverse vulcanization has emerged as a novel procedure to obtain inorganic-organic hybrid polymeric materials. Sulfur is attained as a by-product of oil refining production and makes inverse vulcanization a sustainable process due to a large amount of sulfur without a useful life. In previous studies, vegetable oils were used as a comonomer with sulfur to form copolymers based on sustainable raw material. Nevertheless, compounds from agro-wastes, could be a third comonomer that improves new copolymers bio-applications. In this study, a new series of copolymers with castor oil as vegetable oil and sulfur was formulated by adding a third compoundbearing double bonds or heteroatoms. A study was conducted to assess the antimicrobial capacity and antioxidant activity of the copolymers obtained to demonstrate the benefits of adding a new comonomer to improve their bioactivity. PB Elsevier SN 0142-9418 YR 2022 FD 2022-03 LK https://hdl.handle.net/10272/23018 UL https://hdl.handle.net/10272/23018 LA eng NO Cubero-Cardoso, J., Gómez‐Villegas, P., Santos-Martín, M., Sayago, A., Fernández-Recamales, Á., Fernández de Villarán, R., Cuadri, A. A., Martín-Alfonso, J. E., Borja, R., Fermoso, F. G., León, R., & Urbano, J. (2022). Combining vegetable oils and bioactive compounds via inverse vulcanization for antioxidant and antimicrobial materials. In Polymer Testing (Vol. 109, p. 107546). Elsevier BV. https://doi.org/10.1016/j.polymertesting.2022.107546 NO The authors are grateful to the Regional Government of Andalusia, Junta de Andalucía, Consejería de Economía y Conocimiento and University of Huelva (Project UHU-1257728).The authors also want to express their acknowledgement of Fundación Cátedra Cepsa for kindly supplying the sulfur. DS Repositorio Institucional de la Universidad de Huelva RD 30 may 2026