RT Journal Article
T1 Metal-Catalyzed Postpolymerization Strategies for Polar Group Incorporation into Polyolefins Containing C–C, C═C, and Aromatic Rings
A1 Menendez Rodriguez, Gabril
A1 Díaz Requejo, María Mar
A1 Pérez Romero, Pedro José
AB Polymeric materials bearing polar groups constitute a class of macromolecules with interest in a number of uses. Because the direct synthesis employing polymerization strategies from polar monomers is very often precluded by catalyst poisoning or uncontrolled side reactions, the alternative postpolymerization route consisting in modifying a previously prepared polymer iscontinuously progressing. However, such a posteriori modification depends on the existence of potential reaction sites in the polymer. Because of this, polyolefins are the most challenging  substrates to work with and, among them, the saturated ones. In this contribution, the current state of the art of the metal-catalyzed modification of polyolefins and subsequent polar group incorporation is provided.
PB American Chemical Society
SN 0024-9297
SN 1520-5835 (electrónico)
YR 2021
FD 2021-05-19
LK https://hdl.handle.net/10272/21351
UL https://hdl.handle.net/10272/21351
LA eng
NO Menendez Rodriguez, G., Díaz-Requejo, M. M., & Pérez, P. J. (2021). Metal-Catalyzed Postpolymerization Strategies for Polar Group Incorporation into Polyolefins Containing C–C, C═C, and Aromatic Rings. In Macromolecules (Vol. 54, Issue 11, pp. 4971–4985). American Chemical Society (ACS). https://doi.org/10.1021/acs.macromol.1c00374
NO We acknowledge financial support from the Ministerio de Ciencia e Innovacion (CTQ2017-82893-C2-1-R), Junta de Andalucia (P18-RT-1536), and Universidad de Huelva (P.O.Feder UHU-1260216 and UHU-1254043). DYNASOL SLU is also highly appreciated for financial support.Funding for open access charge: Universidad de Huelva / CBUA
DS Repositorio Institucional de la Universidad de Huelva
RD 30 may 2026