@article{10272/23155,
year = {2016},
month = {10},
url = {https://hdl.handle.net/10272/23155},
abstract = {A new fluorescent acrylamide-type monomer bearing a hydrogen bonding- and polarity-sensitive benzocoumarin fluorophore was synthesized. The absorption spectra, fluorescence spectra, and fluorescence lifetime of a model compound were measured in ten solvents with different hydrogen-bonding abilities and polarities to investigate the sensitivity of the fluorophore to the surrounding environment. These spectroscopic studies demonstrated that the fluorophore emits stronger fluorescence in more protic, polar environments. A fluorescent polymeric thermometer was prepared from N-isopropylacrylamide and the new fluorescent monomer, and it showed good functionality in aqueous solution (e.g., high sensitivity to temperature changes and high chemical stability), indicating the applicability of the herein developed fluorescent monomer for use in functional sensors.},
organization = {We acknowledge the Japan Science and Technology Agency (the Development of Advanced Measurement and Analysis Systems program for S. U.), the Japan Society for the Promotion of Science (Grant-in-Aid for Challenging Exploratory Research 16K14002 for S. U.), and the Spanish Ministry for Economy and Competitiveness (grants CTQ2008-06777-C02-02 and CTQ2014-54729-C2-1-P for U. P. and PhD fellowship BES-2009-012264 and travel grant EEBB-I-13-07155 for P. R.).},
publisher = {Springer},
title = {A fluorescent acrylamide-type monomer bearing an environment-sensitive methoxybenzocoumarin structure for the development of functional polymeric sensors},
doi = {10.1039/c6pp00150e},
author = {Uchiyama, Seiichi and Remón Ruiz, Patricia and Pischel, Uwe and Kawamoto, Kyoko and Gota, Chie},
}