RT Journal Article T1 Rheological behaviour of polymer-modified bituminous mastics : a comparative analysis between physical and chemical modification A1 Shivokhin, Maxim A1 García Morales, Moisés A1 Partal López, Pedro A1 Cuadri Vega, Antonio Abad A1 Gallegos Montes, Críspulo AB Mastic, a bitumen/filler blend which naturally forms when bitumen is mixed with aggregates is the actual product used to bind coarse mineral particles in the asphalt mixtures. As a result, the characterisation of mastics is essential to improve the understanding of the response and performance of asphalt concrete pavements. On the other hand, the lack of experimental data concerning the behaviour of mastics and, above all, polymer-modified mastics has been lately claimed. In that sense, this work presents a comparative analysis between the effect that “physical” and “chemical” modification by polymers exert on mastics prepared by blending modified binders with different contents of calcium carbonate, ranging from 65 to 80 wt.%. Tri-block copolymer SBS and a “reactive” isocyanate-based prepolymer were used as modifying agents in the preparation of the binders. Linear viscoelasticy tests revealed that polymer type exerts, at high temperatures, a significant influence on the binder contribution to the overall rheological properties of the resulting mastic. PB Elsevier SN 0950-0618 SN 1879-0526 (electrónico) YR 2012 FD 2012 LK http://hdl.handle.net/10272/12115 UL http://hdl.handle.net/10272/12115 LA eng NO Shivokhin, M., García Morales, M., Partal López, P., Cuadri Vega, A.A., Gallegos Montes, C.: "Rheological behaviour of polymer-modified bituminous mastics : a comparative analysis between physical and chemical modification". Construction and Building Materials. Vol. 27, n. 1, págs. 234-240, (2012) NO This work is part of a research project sponsored by a MEC-FEDER Programme (Research Project MAT2007-61460) and by a Junta de Andalucía Programme (TEP6689). The authors gratefully acknowledge its financial support. A.A.Cuadri also acknowledges the concession of MEC FPU research fellowship (AP2008-01419). DS Repositorio Institucional de la Universidad de Huelva RD 31 may 2026