@article{10272/19621, year = {2020}, month = {10}, url = {http://hdl.handle.net/10272/19621}, abstract = {The mild generation of nitrogen-centred radicals from N–F reagents has become a convenient synthetic tool. This methodology provides access to the aminative difunctionalisation of alkenes and alkynes and the radical ring-opening of cyclopropanes, among other similar transformations. This review article aims to provide an overview of recent developments of such processes involving radical reactions and N–F reagents using copper-based catalysts.}, organization = {We thank Ministerio de Economía y Competitividad (MINECO) (CTQ2017-82893-C2-1-R) and Universidad de Huelva (PO FEDER 2014-2020 UHU-1254043) for grants.}, publisher = {Royal Society of Chemistry}, title = {Copper-catalysed radical reactions of alkenes, alkynes and cyclopropanes with N–F reagents}, doi = {10.1039/d0ob01743d}, author = {Muñoz Molina, José María and Rodríguez Belderraín, Tomás and Pérez Romero, Pedro José}, }