RT Journal Article T1 Copper-catalysed radical reactions of alkenes, alkynes and cyclopropanes with N–F reagents A1 Muñoz Molina, José María A1 Rodríguez Belderraín, Tomás A1 Pérez Romero, Pedro José AB The mild generation of nitrogen-centred radicals from N–F reagents has become a convenient synthetictool. This methodology provides access to the aminative difunctionalisation of alkenes and alkynes andthe radical ring-opening of cyclopropanes, among other similar transformations. This review article aimsto provide an overview of recent developments of such processes involving radical reactions and N–Freagents using copper-based catalysts. PB Royal Society of Chemistry SN 1477-0520 SN 1477-0539 (electrónico) YR 2020 FD 2020-10 LK http://hdl.handle.net/10272/19621 UL http://hdl.handle.net/10272/19621 LA eng NO Muñoz Molina, J. M., Rodríguez Belderrain, T. & Pérez, P. J. (2020). Copper-catalysed radical reactions of alkenes, alkynes and cyclopropanes with N–F reagents. Organic & Biomolecular Chemistry, 18(43), 8757–8770. DOI: https://doi.org/10.1039/d0ob01743d NO We thank Ministerio de Economía y Competitividad (MINECO) (CTQ2017-82893-C2-1-R) and Universidad de Huelva (PO FEDER 2014-2020 UHU-1254043) for grants. DS Repositorio Institucional de la Universidad de Huelva RD 13 jun 2026