@article{10272/11566, year = {2011}, url = {http://hdl.handle.net/10272/11566}, abstract = {Transition-metal-catalyzed atom transfer radical reactions of halogenated compounds with olefins constitute a versatile tool in organic synthesis within the area of C–C bond forming transformations. The inter- or intramolecular versions, atom transfer radical addition (ATRA) or cyclization (ATRC), respectively, lead to the atom-economic, useful synthesis of compounds that can be further functionalized. This contribution summarizes the recent developments in this area in terms of catalyst design as well as the applicability of this methodology in sequential, domino, or tandem reactions.}, organization = {We thank the Ministerio de Ciencia e Innovacion (grants CTQ2008-00042BQU and CTQ2008-06866-CO2-02/BQU), Consolider Ingenio 2010 (CSD2006-0003), and the Junta de Andalucia (Grant P07-FQM-02794) for financial support.}, publisher = {Wiley-VCH Verlag}, title = {Atom Transfer Radical Reactions as a Tool for Olefin Functionalization : On the Way to Practical Applications}, doi = {10.1002/ejic.201100379}, author = {Muñoz Molina, José María and Rodríguez Belderraín, Tomás and Pérez Romero, Pedro José}, }