@article{10272/25194,
year = {2019},
month = {9},
url = {https://hdl.handle.net/10272/25194},
abstract = {Reversible encapsulation of CH2Cl2 or Xe in a non-porous solid-state molecular organometallic framework of [Rh(Cy2PCH2PCy2)(NBD)][BArF4] occurs in single-crystal to single-crystal transformations. These processes are probed by solid-state NMR spectroscopy, including 129Xe SSNMR. Non-covalent interactions with the -CF3 groups, and hydrophobic channels formed, of [BArF4]− anions are shown to be important, and thus have similarity to the transport of substrates and products to and from the active site in metalloenzymes.},
organization = {We thank the EPSRC (EP/M024210) and SCG Chemicals Co., Ltd, Thailand for funding and Dr Alasdair McKay for the initial synthesis of [2-NBD][(CH2Cl2)0.75⊂BArF4].},
publisher = {Wiley},
title = {Reversible Encapsulation of Xenon and CH2Cl2 in a Solid-State Molecular Organometallic Framework (Guest@SMOM)},
doi = {10.1002/anie.201910539},
author = {Martínez Martínez, Antonio Jesús and Rees, Nicholas H. and Weller, Andrew S.},
}