RT Journal Article
T1 Reversible Encapsulation of Xenon and CH2Cl2 in a Solid-State Molecular Organometallic Framework (Guest@SMOM)
A1 Martínez Martínez, Antonio Jesús
A1 Rees, Nicholas H.
A1 Weller, Andrew S.
AB Reversible encapsulation of CH2Cl2 or Xe in a non-porous solid-state molecular organometallic framework of [Rh(Cy2PCH2PCy2)(NBD)][BArF4] occurs in single-crystal to single-crystal transformations. These processes are probed by solid-state NMR spectroscopy, including 129Xe SSNMR. Non-covalent interactions with the -CF3 groups, and hydrophobic channels formed, of [BArF4]− anions are shown to be important, and thus have similarity to the transport of substrates and products to and from the active site in metalloenzymes.
PB Wiley
SN 0044-8249
SN 1521-3757 (electrónico)
YR 2019
FD 2019-09
LK https://hdl.handle.net/10272/25194
UL https://hdl.handle.net/10272/25194
LA eng
NO Martínez‐Martínez, A. J., Rees, N. H., & Weller, A. S. (2019). Reversible Encapsulation of Xenon and CH2Cl2 in a Solid‐State Molecular Organometallic Framework (Guest@SMOM). In Angewandte Chemie International Edition (Vol. 58, Issue 47, pp. 16873–16877). Wiley. https://doi.org/10.1002/anie.201910539
NO We thank the EPSRC (EP/M024210) and SCG Chemicals Co., Ltd, Thailand for funding and Dr Alasdair McKay for the initial synthesis of [2-NBD][(CH2Cl2)0.75⊂BArF4].
DS Repositorio Institucional de la Universidad de Huelva
RD 1 jun 2026