@article{10272/19640,
year = {2019},
month = {10},
url = {http://hdl.handle.net/10272/19640},
abstract = {The synthesis of novel fluorinated symmetrical and unsymmetrical imidazolium salts as well as their corresponding coinage metal complexes is described. The silver derivatives were prepared using Ag2O as the metal source and the subsequent (NHC)AgX complexes were successfully employed in the preparation of the corresponding Cu(I) and Au(I) complexes through transmetallation reactions. Halide extrusion from (NHC)AuCl complexes in the presence of labile ligands also allowed the isolation of Au(I) cationic complexes [(NHC)Au(L)]X. The molecular structures of relevant examples of the neutral and ionic complexes have been unambiguously determined by X-ray studies.},
organization = {The authors thank Agencia Estatal de Investigación 
(AEI)/FEDER (CTQ2017-82893-C2-1-R, CTQ2016-
75960-P), Red Intecat CTQ2016-81923-REDC, the 
AGAUR (2017 SGR 1257), and CERCA 
Program/Generalitat de Catalunya for financial 
support. M. D. R. thanks the Ministerio de Educación 
y Ciencia (MEC) for a FPU fellowship and C. G.-M. 
thanks Agencia Estatal de Investigación for a FPI 
predoctoral fellowship.},
publisher = {Elsevier},
title = {Coinage metal complexes bearing fluorinated N-Heterocyclic carbene ligands},
doi = {10.1016/j.jorganchem.2019.07.007},
author = {Delgado Rebollo, Manuela and García Morales, Cristina and Maya, Celia and Prieto Cárdenas, María Auxiliadora and Echavarren, Antonio M. and Pérez Romero, Pedro José},
}