RT Journal Article
T1 Make It Green: Copper-Catalyzed Olefin Aziridination in Water with an Iminoiodonane
A1 Borrego, Elena
A1 Pérez Romero, Pedro José
A1 Caballero Bevia, Ana
AB The copper complex Tp(CF3)2,BrCu(NCMe) efficiently catalyses the aziridination of olefins in water using PhI=NTs as the nitrene source, with identical activity than that observed when using dichloromethane as the solvent, under the same experimental conditions. No specific modification of catalyst or substrates are required, nor the presence of additional phase transfer catalyst. Competition experiments and Hammett plots show that the behaviour of the metal centre is the same in both reaction media. This is the first example of a catalytic system employing PhI=NTs for olefin aziridination in water.
PB Wiley
SN 1434-1948
SN 1099-0682 (electrónico)
YR 2021
FD 2021
LK http://hdl.handle.net/10272/20442
UL http://hdl.handle.net/10272/20442
LA eng
NO Borrego, E., Pérez, P. J., Caballero, A.: "Make It Green: Copper-Catalyzed Olefin Aziridination in Water with an Iminoiodonane". Eur. J. Inorg. Chem., págs. 5091–5095, (2021). doi.org/10.1002/ejic.202100825
NO We thank financial support from the Ministerio de Ciencia e Innovación (PID2020-113797RB-C21), Junta de Andalucía (P18-RT-1536) and Universidad de Huelva (P.O.Feder UHU-1260216).Funding for open access charges is given by Universidad deHuelva/CBUA.
DS Repositorio Institucional de la Universidad de Huelva
RD 1 jun 2026