@article{10272/11555, year = {2011}, url = {http://hdl.handle.net/10272/11555}, abstract = {The complexes [Au2M2(C6F5)4(NCMe)2]n (M = Cu, 1; M = Ag, 2) have been tested as catalysts for the functionalization of alkanes by the carbene insertion methodology, using ethyl diazoacetate as the carbene source. Moderate to high conversions have been obtained. The observed selectivities seem to favor the proposal that the active metal for catalysis is the Cu/Ag center, the Au(C6F5)2 unit acting as a spectator ligand in both cases.}, organization = {DGI for funding (CTQ2008-00042/BQU and CTQ2010-20500-C02-02)}, publisher = {Elsevier}, title = {Intermetallic coinage metal-catalyzed functionalization of alkanes with ethyl diazoacetate : gold as a ligand}, doi = {10.1016/j.ica.2011.01.012}, author = {Fuentes Domínguez, María Ángeles and Rodríguez Castillo, María and Monge, Miguel and Olmos, M. Elena and López de Luzuriaga, José M. and Caballero Bevia, Ana and Pérez Romero, Pedro José}, }