RT Journal Article
T1 Intermetallic coinage metal-catalyzed functionalization of alkanes with ethyl diazoacetate : gold as a ligand
A1 Fuentes Domínguez, María Ángeles
A1 Rodríguez Castillo, María
A1 Monge, Miguel
A1 Olmos, M. Elena
A1 López de Luzuriaga, José M.
A1 Caballero Bevia, Ana
A1 Pérez Romero, Pedro José
AB The complexes [Au2M2(C6F5)4(NCMe)2]n (M = Cu, 1; M = Ag, 2) have been tested as catalysts for the functionalizationof alkanes by the carbene insertion methodology, using ethyl diazoacetate as the carbenesource. Moderate to high conversions have been obtained. The observed selectivities seem to favor theproposal that the active metal for catalysis is the Cu/Ag center, the Au(C6F5)2 unit acting as a spectatorligand in both cases.
PB Elsevier
SN 0020-1693
YR 2011
FD 2011
LK http://hdl.handle.net/10272/11555
UL http://hdl.handle.net/10272/11555
LA eng
NO Fuentes, M.A., Rodríguez Castillo, M., Monge, M., Olmos, M. Elena, López de Luzuriaga, J.M., Caballero Bevia, A., Pérez Romero, P.J.: "Intermetallic coinage metal-catalyzed functionalization of alkanes with ethyl diazoacetate : gold as a ligand". Inorganica Chimica Acta. Vol. 369, n. 1, págs. 146-149, (2011). DOI: 10.1016/j.ica.2011.01.012
NO DGI for funding (CTQ2008-00042/BQUand CTQ2010-20500-C02-02)
DS Repositorio Institucional de la Universidad de Huelva
RD 31 may 2026