@article{10272/16790,
year = {2019},
url = {http://hdl.handle.net/10272/16790},
abstract = {The first examples of stable metal complexes with coordinated ethylene and carbon dioxide ligands are reported. Reaction of tris(ethylene) complexes mer-M(C2H4)3(PNP) (M = Mo and W; PNP = 2,6-bis(diphenylphosphinomethyl)pyridine) with CO2 yields the corresponding, mixed cis-M(C2H4)2(CO2)(PNP) derivatives. X-ray studies reveal six-coordinate structures exhibiting η2-ethylene and κ2-C,O carbon dioxide coordination. Remarkably, the formation of the molybdenum CO2 adduct occurs also in the solid state at room temperature, under 4 bar of CO2, in a nearly quantitative manner.},
organization = {We thank MINECO for support with Grants CTQ2017-82893-C2-
1-R and CTQ2017-82893-C2-2-R and a FPI fellowship (MA). A. G.
thanks the Centro de Servicios de Inform´atica y Redes de
Comunicaciones (CSIRC), Universidad de Granada, for
providing the computing time. We thank Francisco Molina for
X-ray structure determination.},
publisher = {Royal Society of Chemistry},
title = {Molybdenum and tungsten complexes with carbon dioxide and ethylene ligands},
doi = {10.1039/c9sc03225h},
author = {Álvarez, María and Galindo, Agustín and Pérez Romero, Pedro José and Carmona, Ernesto},
}