RT Journal Article
T1 The TpxM Core in Csp3–H Bond Functionalization Reactions: Comparing Carbene, Nitrene, and Oxo Insertion Processes (Tpx = Scorpionate Ligand; M = Cu, Ag)
A1 Díaz Requejo, María Mar
A1 Pérez Romero, Pedro José
AB A comparison between three TpxM‐catalyzed (Tpx = scorpionate ligand; M = Cu, Ag) reactions leading to the functionalization of non‐activated, alkane Csp3–H bonds by carbene, nitrene or oxo insertion is presented. Analogies and differences in these transformations are discussed, including main reactive intermediates, selectivity trends and mechanistic interpretations.
PB Wiley
SN 1434-1948
SN 1099-0682 (electrónico)
YR 2020
FD 2020-03
LK http://hdl.handle.net/10272/19643
UL http://hdl.handle.net/10272/19643
LA eng
NO Díaz‐Requejo, M. M., & Pérez, P. J. (2020). The Tp x M Core in C sp 3 –H Bond Functionalization Reactions: Comparing Carbene, Nitrene, and Oxo Insertion Processes (Tp x = Scorpionate Ligand; M = Cu, Ag). European Journal of Inorganic Chemistry, 2020(11–12), 879–885. https://doi.org/10.1002/ejic.201901168
NO Support for this work was provided by the MINECO (CTQ2017-82893-C2-1-R).
DS Repositorio Institucional de la Universidad de Huelva
RD 30 may 2026