RT Journal Article
T1 Homogeneous Metal-Based Catalysis in Supercritical Carbon Dioxide as Reaction Medium
A1 Olmos Verge, Andrea
A1 Asensio, Gregorio
A1 Pérez Romero, Pedro José
AB Above 31.1 degrees C and 73.8 bar, carbon dioxide reaches the supercritical state, being transformed into a fluid (scCO(2)) that has attracted interest in the last few decades as reaction medium for several transition-metal-catalyzed organic transformations. The main feature of this fluid rests on its capability to dissolve large amounts of other gases such as hydrogen, carbon monoxide, ethylene, or even methane and light alkanes. In this manner, very high concentrations of these reactants are available for catalysis. In this contribution a review of the main achievements of the use of transition-metal complexes as catalysts in scCO(2) is presented.
PB American Chemical Society
SN 2155-5435
YR 2016
FD 2016
LK http://hdl.handle.net/10272/16242
UL http://hdl.handle.net/10272/16242
LA eng
NO Olmos, A., Asensio, G., & Pérez, P. J. (2016). Homogeneous Metal-Based Catalysis in Supercritical Carbon Dioxide as Reaction Medium. ACS Catalysis, 6(7), 4265–4280. https://doi.org/10.1021/acscatal.6b00848
NO Support for this work was provided by the MINECO (CTQ2014-52769-CO3-1-R and CTQ2014-52769-CO3-2-R) and the Junta de Andalucia (P10-FQM-06292). A.O. thanks the MINECO for a Juan de la Cierva fellowship (JCI-2011-09184).
DS Repositorio Institucional de la Universidad de Huelva
RD 14 jul 2026