RT Journal Article T1 Biogeochemical indicators (waters/diatoms) of acid mine drainage pollution in the Odiel river (Iberian Pyritic Belt, SW Spain) A1 Córdoba García, Francisco A1 Luís, Ana Teresa A1 Leiva, Mercedes A1 Miguel Sarmiento, Aguasanta A1 Santisteban Fernández, María A1 Fortes Garrido, Juan Carlos A1 Dávila Martín, José Miguel A1 Álvarez Bajo, Osiris A1 Grande Gil, José Antonio AB Odiel river basin is located in the Iberian Pyritic Belt (IPB) and mostly of its tributaries are severely affected by acid mine drainage (AMD). It is originated when pyritic minerals from abandoned mines, especially mineral residues from waste rock dams, get in contact with air and water. Fifteen sampling points were chosen to analyze interactions between diatom communities and water hydrogeochemistry. Considering physicochemical characteristics, sampling points were assigned as highly, moderately, and unpolluted by AMD. No correlation was observed between ecological diversity indexes and physico-chemical parameters. However, a dependency relationship between diatom species distribution and specific pH, conductivity, redox potential, sulfate, and metal concentrations was observed. Cluster analysis based on Pearson correlation and rs values of the non-parametric Spearman correlation allowed to identify Pinnularia acidophila, Pinnularia subcapitata var. elongata, and Eunotia exigua as the main bioindicators of AMD-polluted Odiel streams. Finally, a principal component analysis led to associate the most abundant diatoms species to specific physico-chemical parameters. PB Springer SN 0944-1344 SN 1614-7499 (electrónico) YR 2022 FD 2022-01 LK https://hdl.handle.net/10272/24730 UL https://hdl.handle.net/10272/24730 LA eng NO Córdoba, F., Luís, A.T., Leiva, M. et al. Biogeochemical indicators (waters/diatoms) of acid mine drainage pollution in the Odiel river (Iberian Pyritic Belt, SW Spain). Environ Sci Pollut Res 29, 31749–31760 (2022). https://doi.org/10.1007/s11356-021-18475-2 NO The authors are grateful to the Sustainable Mining Engineering Research Group, Department of Mining, Mechanic, Energetic, and Construction Engineering, Higher Technical School of Engineering, University of Huelva, Spain. DS Repositorio Institucional de la Universidad de Huelva RD 31 may 2026