RT Journal Article
T1 Symmetry projection of the rovibrational functions of methane
A1 Álvarez Bajo, Osiris
A1 Lemus, R.
A1 Carvajal Zaera, Miguel
A1 Pérez Bernal, Francisco
AB In this work we propose a symmetry projection approach to build a rovibrational basis formethane. In our method, symmetry adapted functions are obtained by simultaneous diagonalizationof a set of commuting operators, whose representation is given in terms of direct products ofWigner’s D functions and vibrational matrix representations provided by a local scheme. Theproposed approach is general and permits to obtain in a systematic fashion an orthonormal setof symmetry-projected functions, with good total angular momentum, and carrying the irreduciblerepresentations of the molecular symmetry group.
PB American Institute of Physics
SN 0094-243X
SN 1551-7616 (electrónico)
YR 2010
FD 2010
LK http://hdl.handle.net/10272/9782
UL http://hdl.handle.net/10272/9782
LA eng
NO Ávarez Bajo, O., Lemus, R., Carvajal Zaera, M., Pérez Bernal, F.: "Symmetry projection of the rovibrational functions of methane". AIP Conference Proceedings, Vol. 1323, n. 1, pág. 191-2002 (2010)
DS Repositorio Institucional de la Universidad de Huelva
RD 14 jul 2026