@article{10272/8962, year = {2004}, url = {http://hdl.handle.net/10272/8962}, abstract = {Se/enaíe (SeOf) and sulfate (50/-) have similar structural and chemical properties, and they can play a similar geochemical role. The competition between both anions has been considered in different fields. We present experimental work on crystallisation of Ca(Se04,SC)J-2H20 solid solutions from aqueous solutions. A complete structural characterization of solid solutions by X-ray powder diffraction and thermocalorimetic analysis were carried out. The differences in structural parameters for the different solid compositions have allowed us to quantify the non-ideality of the solid solution and the calculation of a thermodynamic model of this solid solution-aqueous solution system. In addition, the work includes some observations on dehydration behaviour of CaSe0/2H20- CaS042H20 endmembers and solid solutions}, publisher = {Sociedad Geológica de España}, title = {Sustituciones Se042 -S042' en el yeso: un estudio experimental}, title = {SeO/'-SO/' substitution in gypsum: an experimental study}, author = {Fernández González, M. A. and Andara, A. and Prieto, M.}, }