RT Journal Article
T1 Exclusive Aromatic vs Aliphatic C-H Bond Functionalization by Carbene Insertion with Gold-based Catalysts
A1 Rivilla de la Cruz, Iván
A1 Gómez Emeterio, Bella Pilar
A1 Romero Fructos-Vázquez, Manuel
A1 Díaz Requejo, María Mar
A1 Pérez Romero, Pedro José
AB The direct functionalization of aromatic C-H bonds by carbene insertion from diazocompounds catalyzed by gold complexes with N-heterocyclic ligands is described. The reaction is completely selective toward the Csp2-H bonds, other Csp3-H bonds remaining unreacted. A study with a several NHC ligands in Au(I) and Au(III) complexes has been performed. A potential application in profen derivatives has also been developed
PB American Chemical Society
SN 0276-7333
SN 1520-6041 (electrónico)
YR 2011
FD 2011
LK http://hdl.handle.net/10272/11556
UL http://hdl.handle.net/10272/11556
LA eng
NO Rivilla de la Cruz, I., Gómez Emeterio, B.P., Romero Fructos-Vazquez, M., Díaz Requejo, M.M., Pérez Romero, P.J.: "Exclusive Aromatic vs Aliphatic C–H Bond Functionalization by Carbene Insertion with Gold-Based Catalysts".  	Organometallics. Vol. 30 (10), págs. 2855–2860, (2011). DOI: 10.1021/om200206m
NO DGI (CTQ2008-00042BQU and Consolider Ingenio 2010, Grant CSD2006-0003) and Junta de Andalucía (P07-FQM-02870)
DS Repositorio Institucional de la Universidad de Huelva
RD 31 may 2026