@article{10272/23351,
year = {2016},
month = {10},
url = {https://hdl.handle.net/10272/23351},
abstract = {The electrochemical behavior of gentisaldehyde (2,5-dihydroxibenzaldehyde) on a glassy carbon electrode is studied by linear-sweep cyclic voltammetry finding one to three oxidation peaks, depending on both the number of cycles recorded and the pH, and one reduction peak. The oxidation product was the formyl-p-benzoquinone, generated by the oxidation of the biphenolic ring, and not the 2,5-dihydroxybenzoic acid (gentisic acid) that could be formed by oxidation of the aldehyde group. The mechanism proposed at pH < pK1 (8.42) from the analysis of cyclic and convoluted voltammograms involves the loss of an H+ ion from one hydroxyl group, a first quasi-reversible electron transfer to give a radical, and the release of a proton in a third step (the r.d.s.) followed by the second electron transfer to give the product. At pK1 < pH < pK2, the electroactive species is the anion that losses an ion H+ to give the dianion, the process being of the CEE type (chemical-electrochemical-electrochemical steps). At pH > pK2 (10.93) the process becomes of the EE type (electrochemical-electrochemical steps), no H+ ions being involved. Radicals species found justify the antioxidant capacity of gentisaldehyde.},
organization = {Funding from Córdoba University through “Ayudas puente para el desarrollo de proyectos de I+D precompetitivos XX Programa Propio 2016” is gratefully acknowledged.},
publisher = {The Electrochemical Society},
title = {A Contribution on the Elucidation of the Electrooxidation Mechanism of Gentisaldehyde on a Glassy Carbon Electrode},
doi = {10.1149/2.0491614jes},
author = {Estévez Brito, Rafael and Rodríguez Mellado, José Miguel and Palma López, Alberto and Ruiz Montoya, Mercedes and Rodríguez Amaro, Rafael and Mayén, Manuel},
}