RT Journal Article
T1 Ruthenium-Catalyzed Heck-Type Alkenylation of Alkyl Bromides
A1 Muñoz Molina, José María
A1 Pérez Romero, Pedro José
AB The complex [Cp*RuCl(PPh3)2] displays a high catalytic activity forthe Heck-type alkenylation of alkyl bromides, in the first example using this metalunder thermal conditions. The coupling reaction proceeds efficiently with avariety of functionalized tertiary, secondary, and primary alkyl bromides. Thepresence of Hünig’s base has been revealed crucial for this transformation. Preliminarymechanistic studies support the participation of alkyl radicals in thereaction.
PB American Chemical Society
SN 0022-3263
SN 1520-6904 (electrónico)
YR 2019
FD 2019-05-27
LK http://hdl.handle.net/10272/16747
UL http://hdl.handle.net/10272/16747
LA eng
NO Muñoz Molina, J.M., Pérez Romero, P.J.: "Ruthenium-Catalyzed Heck-Type Alkenylation of Alkyl Bromides".  Journal of Organic Chemistry. Vol. 84, 12, (2019). https://doi.org/10.1021/acs.joc.9b00898
NO We thank MINECO for a grant (CTQ2017-82893-C2-1-R). We also thank Francisco Molina for X-ray structure determination
DS Repositorio Institucional de la Universidad de Huelva
RD 1 jun 2026