RT Journal Article
T1 Evidencing an inner-sphere mechanism for NHC-Au(I)- catalyzed carbene-transfer reactions from ethyl diazoacetate
A1 Romero Fructos-Vázquez, Manuel
A1 Urbano Baena, Juan
A1 Díaz Requejo, María Mar
A1 Pérez Romero, Pedro José
AB Kinetic experiments based on the measurement of nitrogen evolution in the reaction of ethyl diazoacetate (N2CHCO2Et, EDA) andstyrene or methanol catalyzed by the [IPrAu]+ core (IPr = 1,3-bis(diisopropylphenyl)imidazole-2-ylidene) have provided evidencethat the transfer of the carbene group CHCO2Et to the substrate (styrene or methanol) takes place in the coordination sphere ofAu(I) by means of an inner-sphere mechanism, in contrast to the generally accepted proposal of outer-sphere mechanisms forAu(I)-catalyzed reactions.
PB Beilstein-Institut
SN 1860-5397 (electrónico)
YR 2015
FD 2015
LK http://hdl.handle.net/10272/11486
UL http://hdl.handle.net/10272/11486
LA eng
NO Romero Fructos-Vázquez, M., Urbano Baena, J., Díaz Requejo, M.M., Pérez Romero, P.J.: "Evidencing an inner-sphere mechanism for NHC-Au(I)- catalyzed carbene-transfer reactions from ethyl diazoacetate". Beilstein Journal of Organic Chemistry. Vol.  11, págs. 2254–2260, (2015). DOI: 10.3762/bjoc.11.245
NO Support  for  this  work  was  provided  by  the  MINECO(CTQ2014-52769-C3-1-R), and the Junta de Andalucía (P10-FQM-06292).
DS Repositorio Institucional de la Universidad de Huelva
RD 2 jun 2026