@article{10272/22449,
year = {2023},
month = {7},
url = {https://hdl.handle.net/10272/22449},
abstract = {Copper catalysts containing alkoxydiaminophosphine (ADAP) ligand catalyze the selective C3- H
functionalization of unprotected indoles upon carbene transfer from donor-acceptor diazo compounds, the N-H bond remaining unaltered during the transformation. Mechanistic studies, including DFT calculations, allows proposing the existence of two competitive pathways, none of them occurring through the formation of cyclopropane intermediates, at variance with previously reported systems.},
organization = {We thank to Ministerio de Ciencia e Innovación for Grants PID2020-113797RB-C21, PID2020-112825RB-I00 and CEX2019-000925-S. We also thank Junta de Andalucía (P18-1536) and Universidad de Huelva (P. O.Feder UHU-202024). I.-G. F thanks the Investigo Program for a contract. L. M.-G. thanks Generalitat de Catalunya for an FI-Agaur predoctoral contract, 2022FI−B2000621.},
publisher = {Wiley},
title = {Selective C−H Bond Functionalization of Unprotected Indoles by Donor-Acceptor Carbene Insertion},
doi = {10.1002/adsc.202300252},
author = {Pizarro Javier, Juan Diego and Morán González, Lucía and González Fernández, Iván and Maseras, Feliu and Romero Fructos-Vázquez, Manuel and Pérez Romero, Pedro José},
}