RT Journal Article
T1 [(PhBP3)Cu(PPh3)] as a surrogate of TpxCuL in homogeneous catalysis (PhBP3 = PhB(CH2PPh2)3; Tpx = hydrotrispyrazolylborate)
A1 Fuentes Domínguez, María Ángeles
A1 Álvarez, Eleuterio
A1 Caballero Bevia, Ana
A1 Pérez Romero, Pedro José
AB The novel complexes [(PhBP3)Cu(L)] (PhBP3 = PhB(CH2PPh2)3, L = PPh3, 1; L = tetrahydrofuran, 2) have been synthesized and spectroscopically and, in the case of 1, structurally characterized. Both complexes undergo dissociation of the PPh3 or THF ligand in solution to deliver the (PhBP3)Cu unit, similar in geometry to and isoelectronic with TpxCu (Tpx = trispyrazolylborate ligand). A complete study of the catalytic properties of 1 has shown that it can be considered as a surrogate of TpxCu. The study includes (a) olefin cyclopropanation, cyclopropenation, aziridination, halocarbon addition, and radical polymerization, (b) X–H (X = O, N) functionalization by carbene insertion, and (c) furan conversion into dihydropyridines. Since the observed activity is quite comparable to that already described for TpxCu complexes, this new catalytic system could become an alternative to the latter.
PB American Chemical Society
SN 0276-7333
YR 2012
FD 2012-01-20
LK https://hdl.handle.net/10272/27611
UL https://hdl.handle.net/10272/27611
LA eng
NO Fuentes, M.A., Álvarez, E., Caballero, A., Pérez, P.J.: "[(PhBP3)Cu(PPh3)] as a surrogate of TpxCuL in homogeneous catalysis (PhBP3 = PhB(CH2PPh2)3; Tpx = hydrotrispyrazolylborate)". Organometallics, Vol. 31, págs. 959–965, (2012). DOI: 10.1021/om201016b
DS Repositorio Institucional de la Universidad de Huelva
RD 31 may 2026