RT Journal Article
T1 The Elusive Palladium-Diazo Adduct Captured: Synthesis, Isolation and Structural Characterization of [(ArNHC-PPh2)Pd(eta(2)-N2C(Ph)CO2Et)]
A1 González Rull, Silvia
A1 Álvarez, Eleuterio
A1 Romero Fructos-Vázquez, Manuel
A1 Rodríguez Belderraín, Tomás
A1 Pérez Romero, Pedro José
AB The first example of a diazo palladium adduct is reported. The complexes [(ArNHC-PPh2) M(eta(N2C)-N-2(Ph) CO2Et)] (M = Ni, 3; M = Pd, 4; ArNHC-PPh2 = 3-(2,6-diisopropylphenyl)- 1-[(diphenylphosphino)ethyl] imidazol-2-ylidene) were prepared by ligand exchange with styrene-coordinated precursors [(ArNHC @ PPh2) M(styrene)] (M = Ni, 1; M = Pd, 2). Complex 4 was fully characterized, including X-ray analyses; this constitutes the first example of a diazo adduct compound with palladium, thereby closing the gap between Groups 8 and 10 regarding this type of compounds.
PB Wiley
SN 0947-6539
SN 1521-3765 (electrónico)
YR 2017
FD 2017
LK http://hdl.handle.net/10272/16194
UL http://hdl.handle.net/10272/16194
LA eng
NO González Rull, S., Álvarez, E., Fructos, M. R., Belderrain, T. R., & Pérez, P. J. (2017). The Elusive Palladium-Diazo Adduct Captured: Synthesis, Isolation and Structural Characterization of [(ArNHC-PPh2 )Pd(η2 -N2 C(Ph)CO2 Et)]. Chemistry - A European Journal, 23(32), 7667-7671. https://doi.org/10.1002/chem.201701362
DS Repositorio Institucional de la Universidad de Huelva
RD 30 may 2026