RT Journal Article
T1 Weak interactions crucial for better enantioselections
A1 Díaz Requejo, María Mar
A1 Pérez Romero, Pedro José
AB In this issue of Chem Catalysis, Schomaker, Liu, and co-workers describe an enantioselective intramolecular silver-catalyzed nitrene transfer (NT) that forms chiral six-membered rings via C–H amidation. They use density functional theory (DFT) calculations to model initial experimental data, which provide crucial insights into the relevance of non-covalent interactions in enantioselection. These findings guide the design of novel ligands that enhance enantiomeric excess in the asymmetric amidation of diverse C–H bonds.
PB Cell Press
YR 2025
FD 2025-08-21
LK https://hdl.handle.net/10272/27602
UL https://hdl.handle.net/10272/27602
LA eng
NO M. Mar Díaz-Requejo, Pedro J. Pérez, Weak interactions are crucial for better enantioselections, Chem Catalysis, Volume 5, Issue 8, 2025, 101496, ISSN 2667-1093, https://doi.org/10.1016/j.checat.2025.101496.
DS Repositorio Institucional de la Universidad de Huelva
RD 31 may 2026