@article{10272/22792,
year = {2010},
url = {https://hdl.handle.net/10272/22792},
abstract = {The spectroscopic and structural characteristics and the relative reactivity of several TpMsCu(olefin) (olefin = ethylene, 1, 1-hexene, 2, allyl ethyl ether, aee, 3, cyclohexene, 4, and styrene, 5) complexes bearing the bulky hydrotris(3-mesitylpyrazolyl)borate ligand have been examined. Experimental data, including an unusual high-field chemical shift in the 1H and 13C NMR spectra, and DFT theoretical calculations support the proposal that the copper−olefin linkage is mainly sustained by σ-donation, lacking a substantial degree of π-back-donation},
organization = {We thank the MICINN (Proyecto CTQ2008−00042BQU, CTQ2008-06866-CO2-02/BQU and Consolider Ingenio 2010 grant CSD2006-0003), the Junta de Andalucía (Proyecto P07-FQM-02794), and the ICIQ Foundation for financial support. C.M. thanks the Ministerio de Educación for a research fellowship},
publisher = {American Chemical Society},
title = {Copper(I)-Olefin Complexes:The Effect of the Trispyrazolylborate Ancillary Ligand in Structure and Reactivity},
doi = {10.1021/om1002705},
author = {Martín Gandul, Carmen and Muñoz Molina, José María and Álvarez, Eleuterio and Locati, Abel and Maseras, Feliu and Rodríguez Belderraín, Tomás and Pérez Romero, Pedro José},
}