@article{10272/24758,
year = {2025},
month = {1},
url = {https://hdl.handle.net/10272/24758},
abstract = {Phosphinoazide complexes of the composition TpBr3M-L (M = Cu, Ag, and L = 2-azido-1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaphosphole) have been synthesized and structurally characterized. Their thermal decomposition led to cyclodiphosphazenes as a result of the metal-mediated coupling of two nitrene units in a process that takes place in both a stoichiometric and catalytic manner. Experimental data have allowed proposing a mechanistic pathway for this new transformation.},
organization = {The authors thank the MinistAerio de Ciencia e Innovación for Grant PID2020-113797RB-C21 and PID2023-146946NB-I00. The authors also thank Junta de Andalucía (P20-00348) and the Universidad de Huelva (P.O. Feder UHU-202016). We also thank funding for open access publication to Universidad de Huelva/CBUA. },
publisher = {American Chemical Society},
title = {Copper and Silver Trispyrazolylborate-Phosphinoazide Complexes: Synthesis, Characterization, and Nitrene Generation},
doi = {10.1021/acs.inorgchem.4c04397},
author = {Ramírez Rodríguez, Manuel and Molina González, Francisco and Díaz Requejo, María Mar and Pérez Romero, Pedro José},
}