RT Journal Article
T1 Copper and Silver Trispyrazolylborate-Phosphinoazide Complexes: Synthesis, Characterization, and Nitrene Generation
A1 Ramírez Rodríguez, Manuel
A1 Molina González, Francisco
A1 Díaz Requejo, María Mar
A1 Pérez Romero, Pedro José
AB Phosphinoazide complexes of the composition TpBr3M-L (M = Cu, Ag, and L = 2-azido-1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaphosphole) have been synthesized and structurally characterized. Their thermal decomposition led to cyclodiphosphazenes as a result of the metal-mediated coupling of two nitrene units in a process that takes place in both a stoichiometric and catalytic manner. Experimental data have allowed proposing a mechanistic pathway for this new transformation.
PB American Chemical Society
SN 0020-1669
SN 1520-510X (electrónico)
YR 2025
FD 2025-01
LK https://hdl.handle.net/10272/24758
UL https://hdl.handle.net/10272/24758
LA eng
NO Rodríguez, M. R., Molina, F., Díaz-Requejo, M. M., & Pérez, P. J. (2025). Copper and Silver Trispyrazolylborate-Phosphinoazide Complexes: Synthesis, Characterization, and Nitrene Generation. In Inorganic Chemistry. American Chemical Society (ACS). https://doi.org/10.1021/acs.inorgchem.4c04397
NO The authors thank the MinistAerio de Ciencia e Innovación for Grant PID2020-113797RB-C21 and PID2023-146946NB-I00. The authors also thank Junta de Andalucía (P20-00348) and the Universidad de Huelva (P.O. Feder UHU-202016). We also thank funding for open access publication to Universidad de Huelva/CBUA. 
DS Repositorio Institucional de la Universidad de Huelva
RD 31 may 2026