@article{10272/24531,
year = {2024},
month = {10},
url = {https://hdl.handle.net/10272/24531},
abstract = {We report the synthesis of cationic 2,6-bisiminopyridine
organoaluminum complexes, [(BIP)AlR2]+, as stable BArF
4 − or PF6 − salts, and their reversible single-electron reduction into
well-defined paramagnetic species, [(BIP·)AlR2]. Four redox
couples, [(BIP)AlR2]+/0, have been fully characterized through
structural, spectroscopic, electrochemical and computational
techniques},
organization = {The authors acknowledge the financial support by the
Ministerio de Ciencia e Innovación MICIN/AEI/10.13039/
501100011033 (grants PID2021-128392NB-100 for J.C.,
PID2019-108292RA-I00 and PID2022-142270OB-I00 for
A.J.M.-M.) and MICIN/NextGenerationEU/PRTR
(CNS2022-136087 for A.J.M.-M), the Thematic Network
“OASIS” RED2022-134074-T, the ERDF/EU, the Junta de
Andalucía (grant P20_00104 for J.C. and P20_00373 for
A.J.M.-M.) and the University of Huelva (UHU-202043 and
EPIT1442023 for A.J.M.-M.). A.J.M.-M. also thanks the
Spanish Research State Agency AEI for a Ramón y Cajal
research (RYC-2017-21783).},
publisher = {American Chemical Society},
title = {Reversible Redox Ligand-Centered Reactivity in 2,6- Bisiminopyridine Aluminum Systems},
doi = {10.1021/acs.inorgchem.4c02664},
author = {Delgado Collado, Juan Manuel and Videa, Hellen and Serrano Laguna, Pablo J. and Fuentes Domínguez, María Ángeles and Álvarez, Eleuterio and Díaz Quintana, Antonio and Martínez Martínez, Antonio Jesús and Rodríguez Delgado, Antonio},
}