RT Journal Article
T1 Reversible Redox Ligand-Centered Reactivity in 2,6- Bisiminopyridine Aluminum Systems
A1 Delgado Collado, Juan Manuel
A1 Videa, Hellen
A1 Serrano Laguna, Pablo J.
A1 Fuentes Domínguez, María Ángeles
A1 Álvarez, Eleuterio
A1 Díaz Quintana, Antonio
A1 Martínez Martínez, Antonio Jesús
A1 Rodríguez Delgado, Antonio
AB We report the synthesis of cationic 2,6-bisiminopyridineorganoaluminum complexes, [(BIP)AlR2]+, as stable BArF4 − or PF6 − salts, and their reversible single-electron reduction intowell-defined paramagnetic species, [(BIP·)AlR2]. Four redoxcouples, [(BIP)AlR2]+/0, have been fully characterized throughstructural, spectroscopic, electrochemical and computationaltechniques
PB American Chemical Society
SN 1520-510X (electrónico)
SN 0020-1669
YR 2024
FD 2024-10
LK https://hdl.handle.net/10272/24531
UL https://hdl.handle.net/10272/24531
LA eng
NO Delgado-Collado, J. M., Videa, H., Serrano-Laguna, P. J., Fuentes, M. Á., Álvarez, E., Díaz Quintana, A., Martínez-Martínez, A. J., Rodríguez-Delgado, A., & Cámpora, J. (2024). Reversible Redox Ligand-Centered Reactivity in 2,6-Bisiminopyridine Aluminum Systems. In Inorganic Chemistry (Vol. 63, Issue 41, pp. 19156–19166). American Chemical Society (ACS). https://doi.org/10.1021/acs.inorgchem.4c02664
NO The authors acknowledge the financial support by theMinisterio de Ciencia e Innovación MICIN/AEI/10.13039/501100011033 (grants PID2021-128392NB-100 for J.C.,PID2019-108292RA-I00 and PID2022-142270OB-I00 forA.J.M.-M.) and MICIN/NextGenerationEU/PRTR(CNS2022-136087 for A.J.M.-M), the Thematic Network“OASIS” RED2022-134074-T, the ERDF/EU, the Junta deAndalucía (grant P20_00104 for J.C. and P20_00373 forA.J.M.-M.) and the University of Huelva (UHU-202043 andEPIT1442023 for A.J.M.-M.). A.J.M.-M. also thanks theSpanish Research State Agency AEI for a Ramón y Cajalresearch (RYC-2017-21783).
DS Repositorio Institucional de la Universidad de Huelva
RD 15 jun 2026