Jiménez Blas, FelipeGalindo, Amparo2020-03-062020-03-062002Blas, F. J., Galindo, A.: "Study of the high pressure phase behaviour of CO2+n-alkane mixtures using the SAFT-VR approach with transferable parameters", Fluid Phase Equilibria 194-197, 501-509 (2002), DOI: 10.1016/S0378-3812(01)00651-30378-38120378-3812http://hdl.handle.net/10272/17578The statistical associating fluid theory for potentials of variable range (SAFT-VR) is used to examine the phase behaviour in the CO2 + n-alkane homologous series. A unique set of transferable parameters for the unlike inter- actions are used which allow the prediction of the phase behaviour of different members of the series with little experimental data. A change in phase behaviour from type II in the van Konynenburg scheme (continuous gas–liquid critical line and liquid–liquid immiscibility at low temperatures) for CO2 + n-dodecane, to type IV (discontinuous gas–liquid critical line and liquid–liquid immiscibility) for CO2 + n-tridecane, and to type III (continuous transi- tion from gas–liquid to liquid–liquid critical behaviour) for CO2 + n-tetradecane is observed in agreement with experimental data.engAtribución-NoComercial-SinDerivadas 3.0 Españahttp://creativecommons.org/licenses/by-nc-nd/3.0/es/High pressurePhase equilibriaStatistical Associating Fluid TheorySAFT-VRCarbon dioxiden-alkanesBinary mixturesGlobal phase behaviourCritical end pointjournal article10.1016/S0378-3812(01)00651-3open access