Barba Lobo, AlejandroGutiérrez Álvarez, IsidoroGutiérrez de San Miguel Herrera, EnriqueBolívar Raya, Juan Pedro2026-02-132026-02-132022Barba-Lobo, A., Gutiérrez-Álvarez, I., San Miguel, E. G., & Bolívar, J. P. (2023). A methodology to determine 212Pb, 212Bi, 214Pb and 214Bi in atmospheric aerosols; Application to precisely obtain aerosol residence times and Rn-daughters’ equilibrium factors. Journal of Hazardous Materials, 445, 130521. https://doi.org/10.1016/j.jhazmat.2022.130521https://hdl.handle.net/10272/27947Progeny of 222Rn and 220Rn, (212Pb, 212Bi, 214Pb and 214Bi) are essential to assess radiological hazard, external and internal doses, residence times and equilibrium factors. Precise measurements of these nuclides are quite complex due to their very short half-lives. This study outlines a new and precise methodology to measure these nuclides. Radon-222 and 220Rn were measured using a radon monitoring system, while their respective progenies were collected in an atmospheric filter using an ASS-500 sampler and measured by gamma-ray spectrometry. The 212Pb concentrations were very similar to the thoron ones, where all 212Bi/212Pb ratios were consistently less than 1. The relative uncertainties, σr, of the 212Pb and 212Bi activity concentrations, and 212Bi/212Pb activity ratio are generally less than 10%. Moreover, 214Pb/222Rn ratios were about 0.7, agreeing well with previous works. The σr for 214Pb, 214Bi and 214Bi/214Pb were generally less than 6%. This methodology was applied to estimate aerosol residence times using the 214Pb/222Rn and 212Bi/212Pb activity ratios, and to obtain equilibrium factors, achieving consistent results. Furthermore, the methodology consistency and validity range were studied with time elapsed between sampling end and counting start, and the sampling durations, finding the optimum times to precisely determine 212Pb, 212Bi, 214Pb and 214Bi.engAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/220Rn – 212Pb – 212Bi222Rn – 214Pb – 214BiAerosol residence timesEquilibrium factorsGamma-ray spectrometryjournal article10.1016/j.jhazmat.2022.130521open access25 Ciencias de la Tierra y del Espacio