Pérez Ruíz, JorgeRosales Martínez, AntonioPérez Romero, Pedro JoséDíaz Requejo, María Mar2026-01-072026-01-072025-04-30Pérez-Ruíz, J., Rosales-Martínez, A., Pérez, P. J., & Díaz-Requejo, M. M. (2025). Introducing the Aziridination of Fluorinated Olefins by Metal‐Catalyzed Nitrene Transfer. Angewandte Chemie International Edition, 64(23), e202419188. https://doi.org/10.1002/anie.202419188https://hdl.handle.net/10272/27606After decades of development of the metal-catalyzed nitrene transfer reactions to olefins, examples involving the use of fluorinated olefins is yet unknown, despite the current importance of fluorocompounds. Herein we describe the use of copper- and silver-based catalysts for a general protocol that converts α- or β- fluoro olefins into the corresponding aziridines in high yields.engAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/Ariidination of fluoro-olefinsCopper catalysisSilver catalysisFluorinated aziridinesNitrene transferjournal article10.1002/anie.202419188open access