Martínez Martínez, Antonio JesúsRees, Nicholas H.Weller, Andrew S.2025-03-172025-03-172019-09Martínez‐Martínez, A. J., Rees, N. H., & Weller, A. S. (2019). Reversible Encapsulation of Xenon and CH2Cl2 in a Solid‐State Molecular Organometallic Framework (Guest@SMOM). In Angewandte Chemie International Edition (Vol. 58, Issue 47, pp. 16873–16877). Wiley. https://doi.org/10.1002/anie.2019105390044-82491521-3757 (electrónico)https://hdl.handle.net/10272/25194Reversible encapsulation of CH2Cl2 or Xe in a non-porous solid-state molecular organometallic framework of [Rh(Cy2PCH2PCy2)(NBD)][BArF4] occurs in single-crystal to single-crystal transformations. These processes are probed by solid-state NMR spectroscopy, including 129Xe SSNMR. Non-covalent interactions with the -CF3 groups, and hydrophobic channels formed, of [BArF4]− anions are shown to be important, and thus have similarity to the transport of substrates and products to and from the active site in metalloenzymes.engAtribución-NoComercial-SinDerivadas 3.0 Españahttp://creativecommons.org/licenses/by-nc-nd/3.0/es/journal article10.1002/anie.201910539open access23 Química