Rediscovering copper-based catalysts for intramolecular carbon–hydrogen bond functionalization by carbene insertion

Martín Gandul, CarmenRodríguez Belderraín, TomásPérez Romero, Pedro José2024-01-042024-01-042009Martín, C., Belderraín, T. R., & Pérez, P. J. (2009). Rediscovering copper-based catalysts for intramolecular carbon–hydrogen bond functionalization by carbene insertion. In Organic & Biomolecular Chemistry (Vol. 7, Issue 22, p. 4777). Royal Society of Chemistry (RSC). https://doi.org/10.1039/b911589g1477-05201477-0539 (electrónico)https://hdl.handle.net/10272/22794A series of Tp(x)Cu complexes (Tp(x) = hydrotrispyrazolylborate ligand) have been tested as catalysts for the decomposition of several diazoacetates and N,N-disubstituted diazoacetamides and the subsequent formation of lactones and lactams, respectively. The complexes containing the ligands Tp(Br3) or Tp(Ms) have provided activities and selectivities for these transformations comparable with or, in some cases, better than the well-known rhodium catalyst Rh(2)(OAc)(4)engAtribución-NoComercial-SinDerivadas 3.0 Españahttp://creativecommons.org/licenses/by-nc-nd/3.0/es/Rediscovering copper-based catalysts for intramolecular carbon–hydrogen bond functionalization by carbene insertionjournal article10.1039/b911589gopen access23 Química