Fuentes Domínguez, María ÁngelesRodríguez Castillo, MaríaMonge, MiguelOlmos, M. ElenaLópez de Luzuriaga, José M.Caballero Bevia, AnaPérez Romero, Pedro José2016-01-112016-01-112011Fuentes, M.A., Rodríguez Castillo, M., Monge, M., Olmos, M. Elena, López de Luzuriaga, J.M., Caballero Bevia, A., Pérez Romero, P.J.: "Intermetallic coinage metal-catalyzed functionalization of alkanes with ethyl diazoacetate : gold as a ligand". Inorganica Chimica Acta. Vol. 369, n. 1, págs. 146-149, (2011). DOI: 10.1016/j.ica.2011.01.0120020-1693http://hdl.handle.net/10272/11555The complexes [Au2M2(C6F5)4(NCMe)2]n (M = Cu, 1; M = Ag, 2) have been tested as catalysts for the functionalization of alkanes by the carbene insertion methodology, using ethyl diazoacetate as the carbene source. Moderate to high conversions have been obtained. The observed selectivities seem to favor the proposal that the active metal for catalysis is the Cu/Ag center, the Au(C6F5)2 unit acting as a spectator ligand in both cases.engAtribución-NoComercial-SinDerivadas 3.0 Españahttp://creativecommons.org/licenses/by-nc-nd/3.0/es/C–H functionalizationDiazocompoundsCarbenesCoinage metalsjournal article10.1016/j.ica.2011.01.012open access