Díaz Requejo, María MarPérez Romero, Pedro José2021-03-292021-03-292020-03Díaz‐Requejo, M. M., & Pérez, P. J. (2020). The Tp x M Core in C sp 3 –H Bond Functionalization Reactions: Comparing Carbene, Nitrene, and Oxo Insertion Processes (Tp x = Scorpionate Ligand; M = Cu, Ag). European Journal of Inorganic Chemistry, 2020(11–12), 879–885. https://doi.org/10.1002/ejic.2019011681434-19481099-0682 (electrónico)http://hdl.handle.net/10272/19643A comparison between three TpxM‐catalyzed (Tpx = scorpionate ligand; M = Cu, Ag) reactions leading to the functionalization of non‐activated, alkane Csp3–H bonds by carbene, nitrene or oxo insertion is presented. Analogies and differences in these transformations are discussed, including main reactive intermediates, selectivity trends and mechanistic interpretations.engAtribución-NoComercial-SinDerivadas 3.0 Españahttp://creativecommons.org/licenses/by-nc-nd/3.0/es/Trispyrazolylborate ligandsCopper and silver catalystsCarbene nitrene oxo• C-H functionalizationAlkane catalysisjournal article10.1002/ejic.201901168open access23 Química