Rivilla de la Cruz, IvánGómez Emeterio, Bella PilarRomero Fructos-Vázquez, ManuelDíaz Requejo, María MarPérez Romero, Pedro José2016-01-112016-01-112011Rivilla de la Cruz, I., Gómez Emeterio, B.P., Romero Fructos-Vazquez, M., Díaz Requejo, M.M., Pérez Romero, P.J.: "Exclusive Aromatic vs Aliphatic C–H Bond Functionalization by Carbene Insertion with Gold-Based Catalysts". Organometallics. Vol. 30 (10), págs. 2855–2860, (2011). DOI: 10.1021/om200206m0276-73331520-6041 (electrónico)http://hdl.handle.net/10272/11556The direct functionalization of aromatic C-H bonds by carbene insertion from diazocompounds catalyzed by gold complexes with N-heterocyclic ligands is described. The reaction is completely selective toward the Csp2-H bonds, other Csp3-H bonds remaining unreacted. A study with a several NHC ligands in Au(I) and Au(III) complexes has been performed. A potential application in profen derivatives has also been developedengAtribución-NoComercial-SinDerivadas 3.0 Españahttp://creativecommons.org/licenses/by-nc-nd/3.0/es/Gold catalysisCarbene transferC-H functionalizationNHC ligandsDiazo compoundsjournal article10.1021/om200206mopen access