González Rull, SilviaÁlvarez, EleuterioRomero Fructos-Vázquez, ManuelRodríguez Belderraín, TomásPérez Romero, Pedro José2019-04-252019-04-252017González Rull, S., Álvarez, E., Fructos, M. R., Belderrain, T. R., & Pérez, P. J. (2017). The Elusive Palladium-Diazo Adduct Captured: Synthesis, Isolation and Structural Characterization of [(ArNHC-PPh2 )Pd(η2 -N2 C(Ph)CO2 Et)]. Chemistry - A European Journal, 23(32), 7667-7671. https://doi.org/10.1002/chem.2017013620947-65391521-3765 (electrónico)http://hdl.handle.net/10272/16194The first example of a diazo palladium adduct is reported. The complexes [(ArNHC-PPh2) M(eta(N2C)-N-2(Ph) CO2Et)] (M = Ni, 3; M = Pd, 4; ArNHC-PPh2 = 3-(2,6-diisopropylphenyl)- 1-[(diphenylphosphino)ethyl] imidazol-2-ylidene) were prepared by ligand exchange with styrene-coordinated precursors [(ArNHC @ PPh2) M(styrene)] (M = Ni, 1; M = Pd, 2). Complex 4 was fully characterized, including X-ray analyses; this constitutes the first example of a diazo adduct compound with palladium, thereby closing the gap between Groups 8 and 10 regarding this type of compounds.engAtribución-NoComercial-SinDerivadas 3.0 Españahttp://creativecommons.org/licenses/by-nc-nd/3.0/es/Carbene transferDiazo ligandsNhc-phosphine ligandPalladium(0) complexesPalladium diazo adductjournal article10.1002/chem.201701362open access