Ramírez Rodríguez, ManuelMolina González, FranciscoDíaz Requejo, María MarPérez Romero, Pedro José2025-01-102025-01-102025-01Rodríguez, M. R., Molina, F., Díaz-Requejo, M. M., & Pérez, P. J. (2025). Copper and Silver Trispyrazolylborate-Phosphinoazide Complexes: Synthesis, Characterization, and Nitrene Generation. In Inorganic Chemistry. American Chemical Society (ACS). https://doi.org/10.1021/acs.inorgchem.4c043970020-16691520-510X (electrónico)https://hdl.handle.net/10272/24758Phosphinoazide complexes of the composition TpBr3M-L (M = Cu, Ag, and L = 2-azido-1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaphosphole) have been synthesized and structurally characterized. Their thermal decomposition led to cyclodiphosphazenes as a result of the metal-mediated coupling of two nitrene units in a process that takes place in both a stoichiometric and catalytic manner. Experimental data have allowed proposing a mechanistic pathway for this new transformation.engAtribución-NoComercial-SinDerivadas 3.0 Españahttp://creativecommons.org/licenses/by-nc-nd/3.0/es/AzidesCopperDegradationOrganic reactionsSilverjournal article10.1021/acs.inorgchem.4c04397open access23 Química