Delgado Collado, Juan ManuelVidea, HellenSerrano Laguna, Pablo J.Fuentes Domínguez, María ÁngelesÁlvarez, EleuterioDíaz Quintana, AntonioMartínez Martínez, Antonio JesúsRodríguez Delgado, Antonio2024-11-272024-11-272024-10Delgado-Collado, J. M., Videa, H., Serrano-Laguna, P. J., Fuentes, M. Á., Álvarez, E., Díaz Quintana, A., Martínez-Martínez, A. J., Rodríguez-Delgado, A., & Cámpora, J. (2024). Reversible Redox Ligand-Centered Reactivity in 2,6-Bisiminopyridine Aluminum Systems. In Inorganic Chemistry (Vol. 63, Issue 41, pp. 19156–19166). American Chemical Society (ACS). https://doi.org/10.1021/acs.inorgchem.4c026641520-510X (electrónico)0020-1669https://hdl.handle.net/10272/24531We report the synthesis of cationic 2,6-bisiminopyridine organoaluminum complexes, [(BIP)AlR2]+, as stable BArF 4 − or PF6 − salts, and their reversible single-electron reduction into well-defined paramagnetic species, [(BIP·)AlR2]. Four redox couples, [(BIP)AlR2]+/0, have been fully characterized through structural, spectroscopic, electrochemical and computational techniquesengAtribución-NoComercial-SinDerivadas 3.0 Españahttp://creativecommons.org/licenses/by-nc-nd/3.0/es/Active ligandsBase-metalComplexesCatalysisEarthPolymerizationReductionIronjournal article10.1021/acs.inorgchem.4c02664open access23 Química